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electroanalytical method
Electroanalytical methods are a class of techniques in analytical chemistry which study an analyte by measuring the potential (volts) and/or current (amperes) in an electrochemical cell containing the analyte. These methods can be broken down into several categories depending on which aspects of the cell are controlled and which are measured. The three main categories are potentiometry (the difference in electrode potentials is measured), coulometry (the cell's current is measured over time), and voltammetry (the cell's current is measured while actively altering the cell's potential).
== Potentiometry ==
Potentiometry passively measures the potential of a solution between two electrodes, affecting the solution very little in the process. The potential is then related to the concentration of one or more analytes. The cell structure used is often referred to as an electrode even though it actually contains ''two'' electrodes: an ''indicator electrode'' and a ''reference electrode'' (distinct from the reference electrode used in the three electrode system). Potentiometry usually uses electrodes made ''selectively'' sensitive to the ion of interest, such as a fluoride-selective electrode. The most common potentiometric electrode is the glass-membrane electrode used in a pH meter.
A variant of potentiometry is chronopotentiometry which consists in using a constant current and measurement of potential as a function of time. It has been iniatiated by Weber〔H. F. Weber, Wied. Ann., 7, 536, 1879〕
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